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Updated: Aug 10, 2026

Synthesis and Characterization of Functionalized Metal-organic Frameworks
Published on: September 5, 2014
Pressure and guest-mediated pore shape modification in a small pore MOF to 1200 bar
Charles J McMonagle1, Gemma F Turner2, Isabelle Jones2
1SNBL at ESRF, Grenoble, France.
Abstract:
Guest-mediated pore-shape modification of the metal-organic framework, Sc2BDC3 upon adsorption of n-pentane and isopentane is examined from 50-1200 bar. Rotation of the BDC linker responsible for the change in pore shape occurs at much lower pressures than previously reported, with distinct adsorption behaviour observed between pentane isomers.
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