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Updated: Aug 23, 2025

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
Published on: July 30, 2017
N-[6-(Di-methyl-amino)-9-phenyl-3H-telluro-xan-then-3-yl-idene]-N-methyl-methanaminium hexa-fluoro-phosphate
Shea Myers1, Patrick Johnson1, Jason B Benedict2
1730 Natural Sciences Complex, University at Buffalo, SUNY, Buffalo, NY 14260-3000, USA.
Abstract:
The title compound C23H23N2Te+·PF6 -, is a monoclinic polymorph of the previously reported triclinic structure [Calitree et al. (2007 ▸). Organometallics, 26, 6248-6257]. In the crystal, parallel offset π-π stacking [shortest centroid-centroid separation = 3.9620 (9) Å] and ionic inter-actions help to establish the packing.
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