ZnSnO₃ based gas sensors for pyridine volatile marker detection in rice aging during storage

This study reports the development of ZnSnO₃ based gas sensors for pyridine detection in rice aging. Pyridine is one of heterocyclic markers formed via Maillard reaction and lipid oxidation. Herein, graphitic carbon nitride (g-C₃N₄) decorated ZnSnO₃ microstructures were obtained through a template-free approach. And the sensing results reveal that 5 wt%g-C₃N₄ decorated ZnSnO₃ exhibited a high sensitivity (47.9), a short response/recovery time (14/120 s) and a low detection limit (0.45 ppm), which is due to the catalysis of g-C₃N₄ nanosheets, the decorated microstructure and the formation of heterojunctions. Meanwhile, the practical experiment demonstrates that the sensitivity towards volatiles generated from Japonica rice aging is 48.7, which is around 4 and 2.5 times higher than those of Indica rice and Polished Glutinous rice, indicating that the sensor has anticipated application in the development of a high-performance E-nose for the quality inspection of rice and other products.