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Updated: Aug 16, 2025

Preparation and Use of Samarium Diiodide SmI2 in Organic Synthesis: The Mechanistic Role of HMPA and NiII Salts in the Samarium Barbier Reaction
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Preparation and Use of Samarium Diiodide SmI2 in Organic Synthesis: The Mechanistic Role of HMPA and NiII Salts in the Samarium Barbier Reaction

Published on: February 4, 2013

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Samarium Diiodide Acting on Acetone-Modeling Single Electron Transfer Energetics in Solution

Luca Steiner1,2, Andreas J Achazi3, Bess Vlaisavljevich4

  • 1Institute of Physical und Theoretical Chemistry, NAWI Graz, Graz University of Technology, Stremayrgasse 9, 8010 Graz, Austria.

Molecules (Basel, Switzerland)
|December 23, 2022
PubMed

Keywords:
HMPA influencecomputational chemistrydensity functional theoryeffective core potentialketyl radicallanthanoide chemistryreduction potential

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