Related Experiment Video
Updated: Aug 16, 2025

08:07
A Micropatterning Assay for Measuring Cell Chirality
Published on: March 11, 2022
2.4K
Imprinting Chirality on Atoms Using Synthetic Chiral Light Fields.
Nicola Mayer1, Serguei Patchkovskii1, Felipe Morales1
1Max-Born-Institute, Max-Born Strasse 2A, 12489 Berlin, Germany.
Physical Review Letters
|December 23, 2022
Summary
Atoms can exhibit chirality through specific quantum states. This study demonstrates exciting atomic chirality with tailored light fields and probing it with photoelectron circular dichroism.
Area of Science:
- Quantum physics
- Atomic physics
- Chirality studies
Background:
- Atoms are typically considered achiral.
- Chiral atomic states can be constructed as superpositions of quantum states.
Purpose of the Study:
- To demonstrate the excitation of chiral atomic states using tailored light fields.
- To show how this induced chirality can be detected.
- To imprint and measure chirality in photoelectrons.
Main Methods:
- Time-dependent Schrödinger equation simulations.
- Excitation using tailored light fields in weak and strong-field regimes.
- Probing with photoelectron circular dichroism.
Main Results:
- Demonstrated creation of time-dependent bound chiral wave packets in sodium atoms.
- Showed that photoelectron circular dichroism can probe time-dependent handedness.
- Imprinted chirality onto photoelectron wave packets via strong-field ionization.
Conclusions:
- Atomic chirality can be experimentally realized and controlled.
- Photoelectron circular dichroism is a viable method for detecting atomic chirality.
- Introduced a new measure to characterize photoelectron wave packet handedness.
Related Concept Videos
Chirality in Nature
13.6K
Chirality is the most intriguing yet essential facet of nature, governing life’s biochemical processes and precision. It can be observed from a snail shell pattern in a macroscopic world to an amino acid, the minutest building block of life. Most of the snails around the world have right-coiled shells because of the intrinsic chirality in their genes. All the amino acids present in the human body exist in an enantiomerically pure state, except for glycine - the sole achiral amino acid.
13.6K
Chirality
24.8K
Chirality is a term that describes the lack of mirror symmetry in an object. In other words, chiral objects cannot be superposed on their mirror images. For example, our feet are chiral, as the mirror image of the left foot, the right foot, cannot be superposed on the left foot.
Chiral objects exhibit a sense of handedness when they interact with another chiral object. For example, our left foot can only fit in the left shoe and not in the right shoe. Achiral objects — objects that have...
Chiral objects exhibit a sense of handedness when they interact with another chiral object. For example, our left foot can only fit in the left shoe and not in the right shoe. Achiral objects — objects that have...
24.8K
Prochirality
3.9K
The concept of prochirality leads to the nomenclature of the individual faces of a molecule and plays a crucial role in the enantioselective reaction. It is a concept where two or more achiral molecules react to produce chiral products. A typical process is the reaction of an achiral ketone to generate a chiral alcohol. Here, the achiral reactant reacts with an achiral reducing agent, sodium borohydride, to generate an equimolar mixture of the chiral enantiomers of the product. For example, an...
3.9K
Molecules with Multiple Chiral Centers
12.0K
Molecules that possess multiple chiral centers can afford a large number of stereoisomers. For instance, while some molecules like 2-butanol have one chiral center, defined as a tetrahedral carbon atom with four different substituents attached, several molecules like butane-2,3-diol have multiple chiral centers. A simple formula to predict the number of stereoisomers possible for a molecule with n chiral centers is 2n. However, there can be a lower number where some of the stereoisomers are...
12.0K
¹H NMR Chemical Shift Equivalence: Enantiotopic and Diastereotopic Protons
1.9K
Replacing each alpha-hydrogen in chloroethane by bromine (or a different functional group) yields a pair of enantiomers. Such protons are called prochiral or enantiotopic and are related by a mirror plane. Enantiotopic protons are chemically equivalent in an achiral environment. Because most proton NMR spectra are recorded using achiral solvents, enantiotopic hydrogens yield a single signal.
In chiral compounds such as 2-butanol, replacing the methylene hydrogens at C3 produces a pair of...
In chiral compounds such as 2-butanol, replacing the methylene hydrogens at C3 produces a pair of...
1.9K
Fischer Projections
13.6K
Learning to draw Fischer projections of molecules and understanding their relevance plays a crucial role in the visual depiction of organic molecules. A Fischer projection is a two-dimensional projection on a planar surface to simplify the three-dimensional wedge–dash representation of molecules. This is especially helpful in the case of molecules with multiple chiral centers that can be difficult to draw. Here, all the bonds of interest are represented as horizontal or vertical lines.
13.6K

