Competitive fiber optic sensors for the highly selective detection of mercury in water

Two competitive fiber optic sensors for the rapid, sensitive, and highly selective detection of mercury in water are designed, fabricated, and evaluated. A wavelength-modulated sensor based on an etched single-mode-multimode-single-mode (E-SMS) optical fiber structure and an intensity-modulated sensor based on fiber optics with a slanted end were fabricated by readily reproducible methods. The sensors were activated with a nanostructured chitosan/maghemite (CS/Fe₂O₃) composite thin film for the selective detection of mercury ions (Hg²⁺) in water. The functionalized sensors were implemented to experimentally validate the potential of CS/Fe₂O₃ thin film for optical sensing of Hg²⁺ in drinking water. The sensor based on the E-SMS structure exhibited a wavelength-modulated response with a sensitivity of up to 290 pm/(µg/mL), and the sensor based on the slanted end structure showed an intensity-modulated response with a sensitivity of -0.07dBm/(µg/mL). Validation of the experimental assay method proves the ability to selectively detect chemical interactions as low as 1 ng/mL (one part per billion) of Hg²⁺ in water for both sensors. The high specificity of the two sensors was demonstrated by evaluating their responses to a number of potentially interfering metal ions in water. These sensors are cost-effective, simple to construct, and easy to implement, which makes them very promising for the on-site detection and monitoring of mercury in bodies of water.