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pH-Triggered Molecular Switch Toward Texture-Regulated Zn Anode.

Shao-Jian Zhang1, Junnan Hao1, Yilong Zhu1

  • 1School of Chemical Engineering & Advanced Materials, The University of Adelaide, Adelaide, SA-5005, Australia.

Angewandte Chemie (International Ed. in English)
|February 28, 2023
PubMed
Summary
This summary is machine-generated.

A novel molecular switch strategy using γ-butyrolactone (GBL) dynamically modulates the zinc (Zn) electrode interface. This approach suppresses parasitic reactions and dendrite formation, enhancing Zn reversibility in aqueous electrolytes.

Keywords:
Dynamic InterfaceHigh Zn DODLow TemperatureMolecular SwitchZn-Ion Battery

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Area of Science:

  • Electrochemistry
  • Materials Science
  • Surface Chemistry

Background:

  • Aqueous zinc (Zn) electrodes suffer from unstable interfaces due to parasitic reactions and dendrite growth.
  • Developing stable and reversible Zn electrodes is crucial for next-generation energy storage devices.

Purpose of the Study:

  • To introduce a dynamic interface modulation strategy for aqueous Zn electrodes.
  • To enhance the reversibility and cyclability of Zn electrodes using a molecular switch approach.

Main Methods:

  • Utilized γ-butyrolactone (GBL) in a ZnCl2/H2O electrolyte to create a dynamic Zn interface.
  • Investigated the molecular switch mechanism triggered by interfacial pH changes during Zn plating and stripping.
  • Analyzed the anchoring of γ-hydroxybutyrate (GHB) on the Zn surface and its effect on hydrogen evolution and morphology.

Main Results:

  • The molecular switch strategy effectively suppressed hydrogen evolution and regulated Zn morphology.
  • Achieved high Zn electrode reversibility with a Coulombic efficiency of 99.8%.
  • Demonstrated high cyclability for Zn||iodine batteries with a 50% depth of discharge.

Conclusions:

  • The dynamic molecular switch strategy significantly enhances the reversibility of aqueous Zn electrodes.
  • This approach offers a promising pathway for developing stable and high-performance zinc-based batteries.
  • Highlights the importance of dynamic interfacial control for advanced electrochemical energy storage.