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Updated: Jul 1, 2025

Highly Stereoselective Synthesis of 1,6-Ketoesters Mediated by Ionic Liquids: A Three-component Reaction Enabling Rapid Access to a New Class of Low Molecular Weight Gelators
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Published on: November 27, 2015

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Illuminating a Solvent-Dependent Hierarchy for Aromatic CH/π Complexes with Dynamic Covalent Glyco-Balances

Laura Díaz-Casado1, Alejandro Villacampa1, Francisco Corzana2

  • 1Departamento de Química Bio-Orgánica, Instituto de Química Orgánica General (IQOG-CSIC), Consejo Superior de Investigaciones Científicas (CSIC), 28006 Madrid, Spain.

JACS Au
|March 1, 2024
PubMed
Summary

Aromatic CH/π interactions are crucial for molecular architecture but their strength varies with environment. This study reveals polarized CH/π interactions can be more stable than cationic ones, challenging existing hierarchies.

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