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Updated: Jun 21, 2025

Synthesis of Nine-atom Deltahedral Zintl Ions of Germanium and their Functionalization with Organic Groups
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Synthesis of Nine-atom Deltahedral Zintl Ions of Germanium and their Functionalization with Organic Groups

Published on: February 11, 2012

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Na[GeF5]·2HF: the first quarternary phase in the H-Na-Ge-F system.

Valentin Bockmair1, Constantin Hoch1, Irina Schusterbauer1

  • 1Department Chemie, Ludwig-Maximilians Universität München, Butenandtstrasse 5-13 (Haus D), D-81377 München, Germany.

Acta Crystallographica. Section C, Structural Chemistry
|July 10, 2024
PubMed
Summary

This study details the second crystal structure of trans-pentafluorogermanate anions in sodium trans-pentafluorogermanate(IV) bis(hydrogen fluoride). The structure features infinite chains of trans-linked octahedra and a network of distorted sodium polyhedra.

Keywords:
crystal structurefluorine chemistrylevelling effectpentagonal bipyramidal coordinationsodium fluorogermanatesuperacidtrans-pentafluorogermanate

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