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Updated: Jun 11, 2025

Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
Published on: February 15, 2016
Mol-ecular structure of tris-[(6-bromo-pyridin-2-yl)meth-yl]amine
Ran Yan1, Zhaohua Dai2, Daniel G Shlian1
1Department of Chemistry Columbia University,New York New York 10027 USA.
Abstract:
Coordination compounds of polydentate nitro-gen ligands with metals are used extensively in research areas such as catalysis, and as models of complex active sites of enzymes in bioinorganic chemistry. Tris(2-pyridyl-meth-yl)amine (TPA) is a tripodal tetra-dentate ligand that is known to form coordination compounds with metals, including copper, iron and zinc. The related compound, tris-[(6-bromo-pyridin-2-yl)meth-yl]amine (TPABr3), C18H15Br3N4, which possesses a bromine atom on the 6-position of each of the three pyridyl moieties, is also known but has not been heavily investigated. The mol-ecular structure of TPABr3 as determined by X-ray diffraction is reported here. The TPABr3 molecule belongs to the triclinic, P space group and displays interesting intermolecular Br⋯Br interactions that provide a stabilizing influence within the molecule.
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