Related Experiment Video
Updated: Jun 8, 2025

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
Published on: August 12, 2013
Ether-Free Alkaline Polyelectrolytes for Water Electrolyzers: Recent Advances and Perspectives
Chuan Hu1,2, Yong Wang2, Young Moo Lee1
1Department of Energy Engineering, College of Engineering, Hanyang University, Seoul, 04763, Republic of Korea.
Abstract:
Anion exchange membrane (AEM) water electrolyzers (AEMWEs) have attracted great interest for their potential as sustainable, environmentally friendly, low-cost sources of renewable energy. Alkaline polyelectrolytes play a crucial role in AEMWEs, determining their performance and longevity. Because heteroatom-containing polymers have been shown to have poor durability in alkaline conditions, this review focuses on ether-free alkaline polyelectrolytes, which are more chemically stable. The merits, weaknesses, and challenges in preparing ether-free AEMs are summarized and highlighted. The evaluation of synthesis methods for polymers, modification strategies, and cationic stability will provide insights valuable for the structural design of future alkaline polyelectrolytes. Moreover, the in situ degradation mechanisms of AEMs and ionomers during AEMWE operation are revealed. This review provides insights into the design of alkaline polyelectrolytes for AEMWEs to accelerate their widespread commercialization.
More Related Videos
Related Concept Videos
Ion Exchange
Aldehydes and Ketones with Water: Hydrate Formation
The formation of hydrates is a reversible reaction. Hydrate formation is influenced by steric and electronic factors accompanying the alkyl substituents on the carbonyl group: The rate of hydrate formation increases with a decrease in the number of alkyl groups attached to the carbonyl carbon. Hence,...
Preparation of Alcohols via Addition Reactions
The acid-catalyzed addition of water to the double bond of alkenes is a large-scale industrial method used to synthesize low-molecular-weight alcohols. An acidic atmosphere is required to allow the hydrogen in the water molecule to act as an electrophile and attack the double bond in an alkene. The addition of a proton to the double bond creates a carbocation intermediate. The proton preferentially bonds to the less substituted end of the double bond to create a more stable carbocation...
Ethers from Alcohols: Alcohol Dehydration and Williamson Ether Synthesis
Ethers can be prepared from organic compounds by various methods. Some of them are discussed below,
Preparation of Ethers by Alcohol Dehydration
In this method, in the presence of protic acids, alcohol dehydrates to produce alkenes and ethers under different conditions. For example, in the presence of sulphuric acid, dehydration of ethanol at 413 K yields ethoxyethane, whereas it yields ethene at 443 K.
Acid-Catalyzed Hydration of Alkenes
Electrolyte and Nonelectrolyte Solutions

