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Detecting single-point isomeric differences in polymer chains by MOF column chromatography.

Nobuhiko Hosono1, Yu Kono1, Nagi Mizutani2

  • 1Department of Applied Chemistry, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan. nhosono@g.ecc.u-tokyo.ac.jp.

Chemical Communications (Cambridge, England)
|November 4, 2024
PubMed
Summary

Metal-organic frameworks (MOFs) in liquid chromatography allow for polymer recognition by threading polymers into nanopores. This method identifies subtle isomeric differences in polymer structures based on adsorption and insertion kinetics.

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