The properties of potato starch with different moisture content treated by cold plasma:Structure, physicochemical and...

To investigate the effect and mechanism of water on the structure, physicochemical properties, and in vitro digestibility of starch treated with CP, different moisture content (16.7 %, 28.6 %, 37.5 %, 44.4 %, and 50 %, w/w) were used, followed by treatment with CP (40 V, 1 A, 3 mins). Results show that CP treatment preserves the Maltese cross pattern, crystal morphology, and Fourier transform infrared spectroscopy spectra of potato starch. However, significant changes were observed in molecular weight, chain length distribution, average particle size, ordered structure, and relative crystallinity. As moisture content increased, the etching effect on the particle surface intensified, leading to further reductions in molecular weight and ordered structure. Concurrently, amylose content, solubility, relative crystallinity, and resistant starch content increased. At higher water levels, water molecules exhibited protective effects, mitigating CP-induced structural damage by reducing etching and loss of molecular weight. These findings suggest that the role of water in CP treatment is complex and provide insights into the interaction between CP and water in starch properties, highlighting its potential applications in starch-based foods.