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Imaging Bias-Driven Domain Wall Motion With Scanning Oscillator Piezoresponse Force Microscopy
Shivaranjan Raghuraman1, Rama K Vasudevan1, Jan-Chi Yang2
1Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, 1 Bethel Valley Road, Oak Ridge, TN, TN 37830, USA.
Small Methods
|January 10, 2025
Summary
New scanning oscillator piezoresponse force microscopy visualizes nanoscale ferroelectric domain wall motion. This technique reveals domain wall energetics, showing a thermally activated flow regime on the millisecond timescale.
Area of Science:
- Materials Science
- Condensed Matter Physics
- Nanotechnology
Background:
- Ferroelectric domain wall dynamics are crucial for understanding materials properties.
- Piezoresponse force microscopy (PFM) has been instrumental in studying domain wall motion.
- Investigating sub-coercive domain wall dynamics requires advanced techniques with high temporal and spatial resolution.
Purpose of the Study:
- To develop and apply a novel technique for visualizing ferroelectric domain wall dynamics.
- To investigate the energetics of field-driven domain wall motion.
- To extend the study of domain wall dynamics to new regimes and timescales.
Main Methods:
- Utilizing scanning oscillator piezoresponse force microscopy (SO-PFM).
- Applying time- and location-varying electric fields.
- Directly visualizing domain wall position as a function of applied electric field.
Main Results:
- SO-PFM enables direct visualization of domain wall position under varying electric fields.
- The study provides insights into the energetics of field-driven ferroelectric domain wall motion.
- Domain wall motion was observed to follow a thermally activated flow regime on the millisecond timescale.
Conclusions:
- Scanning oscillator PFM is a powerful tool for studying nanoscale ferroelectric domain wall dynamics.
- The findings contribute to understanding the fundamental mechanisms governing ferroelectric domain wall behavior.
- This research opens new avenues for exploring ferroelectric materials and devices.

