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Related Concept Videos

Spin–Spin Coupling: Two-Bond Coupling (Geminal Coupling)01:20

Spin–Spin Coupling: Two-Bond Coupling (Geminal Coupling)

Two NMR-active nuclei bonded to a central atom can be involved in geminal or two-bond coupling. Geminal coupling is commonly seen between diastereotopic protons in chiral molecules and unsymmetrical alkenes, among others.
The central atom need not be NMR-active because its electrons are affected by the electron polarization of the spin-active atoms. However, spin information is transmitted less effectively than in one-bond coupling, and 2J values are usually weaker than 1J values. The energy of...
¹H NMR: Long-Range Coupling01:27

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The coupling interactions of nuclei across four or more bonds are usually weak, with J values less than 1 Hz. While these are usually not observed in spectra, the presence of multiple bonds along the coupling pathway can result in observable long-range coupling.
In alkenes, spin information is communicated via σ–π overlap, as seen in allylic (four-bond) and homoallylic (five-bond) couplings. These coupling interactions are stronger when the σ bond is parallel to the alkene π orbitals.

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High-efficiency, cryogenic-compatible grating couplers on an AlN-on-sapphire platform through bottom-side coupling.

Yiyu Zhou, Mohan Shen, Chunzhen Li

    Optics Letters
    |January 31, 2025
    PubMed
    Summary

    We enhanced grating coupler transmission efficiency using bottom-side coupling on sapphire substrates. This method achieves 42% efficiency for aluminum nitride photonic devices, even at cryogenic temperatures.

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    Area of Science:

    • Photonics
    • Materials Science
    • Optoelectronics

    Background:

    • Sapphire substrates are widely used for wide-bandgap III-nitride photonic devices.
    • High refractive index of sapphire leads to low transmission efficiency in conventional grating couplers.
    • Efficient light coupling is crucial for integrated photonic applications.

    Purpose of the Study:

    • To significantly enhance transmission efficiency in grating couplers on sapphire substrates.
    • To investigate a novel bottom-side coupling technique.
    • To assess the performance of grating couplers at cryogenic temperatures.

    Main Methods:

    • Proposed and demonstrated a bottom-side coupling method.
    • Utilized a metal reflector on the top side and fiber array on the bottom side of the substrate.
    • Experimentally tested aluminum nitride (AlN) on sapphire grating couplers at telecom wavelengths.

    Main Results:

    • Achieved a maximum transmission efficiency of 42% per coupler.
    • Demonstrated robust performance at cryogenic temperatures as low as 3 K.
    • Verified performance for both transverse-electric (TE) and transverse-magnetic (TM) modes.

    Conclusions:

    • Bottom-side coupling effectively enhances transmission efficiency for grating couplers on sapphire.
    • The developed grating couplers exhibit excellent performance under cryogenic conditions.
    • This technique is beneficial for sapphire-based photonic applications requiring low coupling loss and low-temperature operation.