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Updated: May 15, 2025

Syntheses, Crystallization, and Spectroscopic Characterization of 3,5-Lutidine N-Oxide Dehydrate
Published on: April 24, 2018
Synthesis, crystal structure and Hirshfeld surface analysis of
Gulrukh Salieva1,2, Tursunali Kholikov1, Rasul Ya Okmanov3
1National University of Uzbekistan named after Mirzo Ulugbek 4 University St Tashkent 100174 Uzbekistan.
Abstract:
The title compound, C13H16N4S (DAMP-DMB), was synthesized through the reaction of 2,4-di-methyl-benzyl chloride with di-amino-pyrimidine-thiol. Single-crystal X-ray diffraction analysis confirmed that the compound crystallizes in the monoclinic crystal system, space group P21/c. The asymmetric unit contains a single mol-ecular entity. Structural examination revealed the presence of a dimeric arrangement consolidated by N-H⋯N hydrogen-bonding inter-actions. Additionally, Hirshfeld surface analysis indicated that H⋯H, N⋯H, C⋯H, and S⋯H contacts account for 98.9% of the total inter-molecular inter-actions to the Hirshfeld surface.
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