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Advancing Tomographic Volumetric Printing Via Oxygen Inhibition Control: Improved Accuracy and Large-Volume

Yujie Zhang1, Katherine Houlahan1, Daniel Webber1

  • 1National Research Council Canada, Ottawa, ON, K1N 5A2, Canada.

Advanced Materials (Deerfield Beach, Fla.)
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Summary
This summary is machine-generated.

This study introduces a chemical strategy to overcome oxygen inhibition in tomographic volumetric additive manufacturing (TVAM) 3D printing. N-methyldiethanolamine (MDEA) enables large-volume, high-resolution prints by sustaining polymerization without compromising light penetration.

Keywords:
(meth)acrylate photopolymerizationlarge‐volume printingoxygen inhibitionprint fidelitytomographic volumetric additive manufacturing

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Area of Science:

  • Additive Manufacturing
  • Polymer Chemistry
  • Photopolymerization

Background:

  • Tomographic volumetric additive manufacturing (TVAM) offers rapid 3D printing of complex structures.
  • Oxygen inhibition and limited light penetration in photoresins restrict TVAM's print size and quality.
  • Current TVAM methods struggle with scalability due to these limitations.

Purpose of the Study:

  • To develop a chemical strategy to mitigate oxygen inhibition in TVAM.
  • To enable high-resolution and large-volume printing in (meth)acrylate-based systems.
  • To overcome limitations of photoinitiator concentration and light penetration.

Main Methods:

  • Investigated amine, thiol, and phosphine additives to control oxygen inhibition.
  • Identified N-methyldiethanolamine (MDEA) as a promising additive.
  • Incorporated MDEA into low-photoinitiator (PI) photoresins for TVAM.

Main Results:

  • MDEA effectively regenerated propagating radicals, sustaining polymerization.
  • Achieved high-resolution printing with a root-mean-square surface deviation of 0.175 mm.
  • Enabled large-volume printing up to 60 mm, a 16-fold increase in print volume.
  • Demonstrated high-throughput fabrication of multiple complex parts.

Conclusions:

  • The chemical strategy effectively overcomes oxygen inhibition in (meth)acrylate TVAM.
  • MDEA enables scalable, high-volume, high-resolution additive manufacturing.
  • This approach unlocks new possibilities for advanced 3D printing applications.