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Scale-up Chemical Synthesis of Thermally-activated Delayed Fluorescence Emitters Based on the Dibenzothiophene-S,S-Dioxide Core
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High-Yielding, Scalable Synthesis of 5,15-Dioxaporphyrin

Taiyou Tsutsumi1, Takanori Iwasaki1, Soji Shimizu1

  • 1Department of Applied Chemistry, Graduate School of Engineering and Center for Molecular Systems (CMS), Kyushu University, Fukuoka 819-0395, Japan.

The Journal of Organic Chemistry
|November 24, 2025
PubMed
Summary

We developed a scalable synthesis for 5,15-Dioxaporphyrin (DOP), a molecule with antiaromatic properties. This improved method increases yield and simplifies procedures, enabling new research and the creation of its first palladium complex.

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