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Updated: Mar 18, 2026

Ultrahigh Density Array of Vertically Aligned Small-molecular Organic Nanowires on Arbitrary Substrates
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Ultralight High-Entropy Nanowire Scaffolds for Extreme-Temperature Functionality.

Cameron S Jorgensen1,2,3, Corisa Kons1, William Stallions1

  • 1Materials Science and Engineering, University of Tennessee, Knoxville, Tennessee 37996, United States.

ACS Applied Materials & Interfaces
|March 17, 2026
PubMed
Summary
This summary is machine-generated.

We developed ultralight, high-entropy alloy (HEA) metamaterials using entropy engineering and structural porosity. These novel materials offer metal-like functionality at extremely low densities for demanding applications.

Keywords:
aerogelelectrodepositionferromagnetismfreeze-castinghigh-entropy alloyslow-densitynanowiresultralight metamaterials

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Area of Science:

  • Materials Science
  • Nanotechnology
  • Metallurgy

Background:

  • High-entropy alloys (HEAs) offer tunable properties but suffer from high density.
  • Lightweight materials are crucial for advanced applications, yet traditional metals are often too dense.

Purpose of the Study:

  • To engineer lightweight functional materials by combining high-entropy alloys with structural porosity.
  • To achieve metal-like properties at ultralow densities using entropy-architected metamaterials.

Main Methods:

  • Electrodeposition of FeCoNiCrCu HEA nanowires into porous templates.
  • Freeze-casting to create 3D "bird's nest" scaffolds with densities <1% of bulk metal.
  • Structural, magnetic, and thermal property characterization.

Main Results:

  • Achieved ultralow density metamaterials (<1% of bulk metal density).
  • Retained disordered face-centered-cubic phase with Curie temperatures >1000 K.
  • Demonstrated thermal diffusivity comparable to titanium alloys (≈0.211 mm² s⁻¹).
  • Identified nanoscale Cu segregation enhancing magnetic ordering and thermal stability.

Conclusions:

  • Entropy-architected nanowire metamaterials offer a pathway to ultralightweight functional materials.
  • Co-engineering configurational entropy and architectural hierarchy enables high-temperature performance.
  • These materials are suitable for extreme-environment applications requiring low density and high functionality.