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Jiaqi Zhu1, Ziyi Gao1, Guoli Zhang1

  • 1Department of Chemistry, Northeastern University, Shenyang 110819, China. sunxiaoqi@mail.neu.edu.cn.

Chemical Communications (Cambridge, England)
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Diazonium Group Substitution: –OH and –H01:19

Diazonium Group Substitution: –OH and –H

Nitrous acid, a weak acid, is prepared in situ via the reaction of sodium nitrite with a strong acid under cold conditions. This nitrous acid prepared in situ reacts with primary arylamines to form arenediazonium salts. Such reactions are known as diazotization reactions. As shown in Figure 1, the formation of arenediazonium salts begins with the decomposition of nitrous acid in an acidic solution to give nitrosonium ions.