Valorization of Keratin Waste as a Functional Precursor for PLA/SBS Composite Adsorbent Films

This study investigated the valorization of keratin extracted from sheep wool waste for the preparation of PLA/SBS/Keratin composites as potential adsorbents for the removal of chromium (Cr) from synthetic water. A flexible formulation containing 75 wt% PLA and 25 wt% SBS was selected for the incorporation of 10 wt%, 20 wt%, and 30 wt% keratin. The morphology and structural characteristics of keratin and PLA-based composites were analyzed using SEM and FT-IR spectroscopy. The mechanical and thermal properties of the prepared composites were investigated using TGA and DMA analyses. The adsorption experiments revealed that keratin exhibited an adsorption capacity of 57.57 mg g^-1 of Cr(VI) removal efficiency, while the PLA/SBS formulation containing 10 wt% keratin achieved a removal efficiency of total Cr of 55.41%. After three regeneration cycles, the removal efficiency decreased by approximately half of the total Cr removal.