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Metal supported on dendronized magnetic nanoparticles: highly selective hydroformylation catalysts

Raed Abu-Reziq1, Howard Alper, Dashan Wang

  • 1Centre for Catalysis Research and Innovation, University of Ottawa, 10 Marie Curie, Ottawa, Ontario, Canada K1N 6N5.

Journal of the American Chemical Society
|April 13, 2006
PubMed

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Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...