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Updated: Jun 20, 2026

Resonance Raman Spectroscopy of Extreme Nanowires and Other 1D Systems
Published on: April 28, 2016
Coherent, nonlinear two-phonon Raman spectra of diamond.
This study reports the first observation of a second-order Raman spectrum using coherent Raman spectroscopy. Optically heterodyned Raman-induced Kerr-effect spectroscopy achieved high sensitivity for diamond
Area of Science:
- Solid-state physics
- Spectroscopy
Background:
- Spontaneous Raman scattering is a common technique for material analysis.
- Coherent Raman spectroscopy offers enhanced sensitivity and resolution.
Purpose of the Study:
- To report the first observation of a second-order Raman spectrum using coherent Raman spectroscopy.
- To investigate two-phonon Raman peaks in diamond with high sensitivity.
Main Methods:
- Optically heterodyned Raman-induced Kerr-effect spectroscopy.
- High-sensitivity Raman spectroscopy on a highly fluorescent diamond sample.
Main Results:
- Achieved sensitivity exceeding spontaneous scattering and other coherent Raman techniques.
- Measured the one-phonon peak frequency at 1333.1 ± 0.5 cm⁻¹.
- Measured the sharp two-phonon peak frequency at 2668.6 ± 0.5 cm⁻¹.
Conclusions:
- Demonstrated the capability of optically heterodyned Raman-induced Kerr-effect spectroscopy for detecting second-order Raman spectra.
- The results validate the technique for analyzing phonon interactions in materials like diamond.
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