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Highly efficient N-heterocyclic carbene/pyridine-based ruthenium sensitizers: complexes for dye-sensitized solar

Wei-Chun Chang1, Huei-Siou Chen, Ting-Yu Li

  • 1Department of Chemistry, National Central University, Chung-Li, Taiwan 32001, ROC.

Angewandte Chemie (International Ed. in English)
|September 22, 2010
PubMed
Abstract

No abstract available in PubMed .

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The absorption of UV–visible light by conjugated systems causes the promotion of an electron from the ground state to the excited state. Consequently, photochemical electrocyclic reactions proceed via the excited-state HOMO rather than the ground-state HOMO. Since the ground- and excited-state HOMOs have different symmetries, the stereochemical outcome of electrocyclic reactions depends on the mode of activation; i.e., thermal or photochemical.
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