Related Experiment Video
Updated: May 21, 2026

11:42
Fabrication of Gate-tunable Graphene Devices for Scanning Tunneling Microscopy Studies with Coulomb Impurities
Published on: July 24, 2015
Structure and electronic transport in graphene wrinkles
Wenjuan Zhu1, Tony Low, Vasili Perebeinos
1IBM Thomas J. Watson Research Center, Yorktown Heights, New York 10598, United States.
Nano Letters
|June 1, 2012
Summary
Wrinkles in large-scale graphene films collapse into standing structures due to van der Waals forces. This morphology limits conductance and creates anisotropic resistivity, impacting graphene electronics.
Area of Science:
- Materials Science
- Condensed Matter Physics
- Nanotechnology
Background:
- Wrinkling is common in 2D membranes, especially during large-scale graphene growth on metal substrates.
- The structural and electronic properties of these wrinkles are not well understood despite their impact on graphene electronics.
Purpose of the Study:
- To investigate the morphology and electronic properties of wrinkles in large-scale graphene.
- To understand the physical mechanisms behind wrinkle formation and their impact on electrical transport.
Main Methods:
- Atomic force microscopy (AFM) was used to survey graphene wrinkle morphology.
- Energetic calculations were performed to explain morphological transitions.
- Quantum transport calculations simulated conductance through collapsed wrinkle structures.
- Systematic electrical resistivity measurements were conducted on devices with folded wrinkles.
Main Results:
- Graphene wrinkles reach a maximum height before folding over, collapsing into narrow standing structures due to van der Waals forces.
- Conductance in collapsed wrinkles is limited by a density-of-states bottleneck and interlayer tunneling.
- Folded wrinkles exhibit distinct electrical resistivity anisotropy, consistent with simulations.
Conclusions:
- The study reveals a strong coupling between graphene wrinkle morphology and electronic properties.
- Understanding these collapsed wrinkle structures is crucial for optimizing large-scale graphene electronics for high-speed applications.
Related Concept Videos
The de Broglie Wavelength
In the macroscopic world, objects that are large enough to be seen by the naked eye follow the rules of classical physics. A billiard ball moving on a table will behave like a particle; it will continue traveling in a straight line unless it collides with another ball, or it is acted on by some other force, such as friction. The ball has a well-defined position and velocity or well-defined momentum, p = mv, which is defined by mass m and velocity v at any given moment. This is the typical...
Network Covalent Solids
Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
Structure of Benzene: Kekulé Model
In 1865, August Kekule suggested the structure of benzene according to the structural theory of organic chemistry based on the three assertions—formula of benzene is C6H6, all the hydrogens of benzene are equivalent, and each carbon must have four bonds due to its tetravalency.
He proposed that benzene has a cyclic structure of six carbon atoms attached to one hydrogen atom each, with three alternating pi bonds.
He proposed that benzene has a cyclic structure of six carbon atoms attached to one hydrogen atom each, with three alternating pi bonds.
Fermi Level Dynamics
The vacuum level denotes the energy threshold required for an electron to escape from a material surface. It is usually positioned above the conduction band of a semiconductor and acts as a benchmark for comparing electron energies within various materials.
Electron affinity in semiconductors refers to the energy gap between the minimum of its conduction band and the vacuum level and it is a critical parameter in determining how easily a semiconductor can accept additional electrons.
The work...
Electron affinity in semiconductors refers to the energy gap between the minimum of its conduction band and the vacuum level and it is a critical parameter in determining how easily a semiconductor can accept additional electrons.
The work...

