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Updated: May 20, 2026

A Study of the Complexation of Mercury(II) with Dicysteinyl Tetrapeptides by Electrospray Ionization Mass Spectrometry
Published on: January 8, 2016
Dichlorido[methyl 2-(quinolin-8-yl-oxy-κ(2)N,O)acetate-κO]mercury(II)
Yu-Hong Wang1, Xue-Hua Zhu, Rui-Feng Song
1School of Chemistry and Bioengineering, Suzhou University of Science and Technology, Suzhou 215009, People's Republic of China.
Abstract:
In the neutral title complex, [HgCl(2)(C(12)H(11)NO(3))], the Hg(II) ion is penta-coordinated by two Cl atoms, one N atom and two weakly coordinating O atoms from the methyl 2-(quinolin-8-yl-oxy)acetate ligand. The coordination around the Hg(II) ion may be described as highly distorted trigonal-bipyramidal. Centrosymmetric dimers are formed by an additional weak Hg⋯Cl inter-action, leading to a distorted octa-hedral coordination geometry around the Hg(II) ion.
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