Generation of coherent phonons in a CdTe single crystal using an ultrafast two-phonon laser-excitation process

The detection-energy dependence of a coherent phonon in a (001) CdTe crystal, generated by ultrashort laser pulses with the center energy transparent or opaque to the sample, is investigated using a spectrally resolved pump-probe method. At the excitation in the transparent region, the detection-energy dependence of the phonon amplitude has two peaks at the energy shifted by one times the phonon energy of CdTe from the center energy of the probe pulses. On the other hand, the amplitude in the opaque region shows two peaks at the energy shifted by about two times the phonon energy. This difference occurs even though the observed energies of the coherent phonons in both regions are the same as that of the longitudinal optical phonon of CdTe. The energy shifts in the detection-energy dependence imply that the emission and absorption of one phonon and two phonons in the transparent and opaque regions, respectively, are implicated in coherent phonon generation. In this study, the detection-energy dependence is examined from the viewpoint of the third-order nonlinear susceptibility based on the impulsive stimulated Raman scattering process under nonresonant and resonant conditions.