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Tuning Oxide Properties by Oxygen Vacancy Control During Growth and Annealing
Published on: June 9, 2023
A Study of the Variability in Contact Resistive Random Access Memory by Stochastic Vacancy Model
Yun-Feng Kao1, Wei Cheng Zhuang1, Chrong-Jung Lin1
1Microelectronics Laboratory, Institute of Electronics Engineering, National Tsing Hua University, Hsinchu, 300, Taiwan.
Variability in resistive random access memory (RRAM) cells stems from oxygen vacancies. This study models RRAM behavior, linking initial states to switching characteristics, and proposes a training scheme to mitigate variability.
Area of Science:
- Materials Science
- Electrical Engineering
- Solid State Physics
Background:
- Resistive random access memory (RRAM) cell variability is a major obstacle for high-density RRAM array development.
- Stochastic oxygen vacancy generation and recombination are widely considered the primary cause of resistive switching variability in transition metal oxide films.
Purpose of the Study:
- To establish a stochastic model linking RRAM cell initial states to subsequent switching characteristics.
- To investigate the impact of oxygen vacancy concentration and distribution on RRAM performance using simulations.
- To propose a method for reducing variability in RRAM devices.
Main Methods:
- Analysis of experimental data to develop a stochastic model.
- Monte Carlo simulation combining a conduction network model and trap-assisted tunneling mechanism.
- Experimental verification using contact RRAM arrays.
Main Results:
- A stochastic model was established, accurately predicting RRAM characteristics based on initial states.
- The model demonstrated the influence of intrinsic oxygen vacancy concentration and distribution.
- A strong correlation between forming characteristics and initial states, linked to pre-existing oxygen vacancies, was verified.
- Measurement data from RRAM arrays showed good agreement with model projections.
Conclusions:
- Intrinsic oxygen vacancies are a key source of variability in contact RRAM devices.
- The developed model provides a comprehensive understanding of RRAM variability mechanisms.
- A reset training scheme can effectively reduce variability in subsequent RRAM states.
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