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Updated: Feb 6, 2026

Spatial Separation of Molecular Conformers and Clusters
Published on: January 9, 2014
{Np38} clusters: the missing link in the largest poly-oxo cluster series of tetravalent actinides
Nicolas P Martin1, Christophe Volkringer, Pascal Roussel
1Unité de Catalyse et Chimie du Solide (UCCS), UMR, CNRS 8181, Université de Lille, École Nationale Supérieure de Chimie de Lille Centrale Lille, Université Artois, Lille 59000, France. thierry.loiseau@ensc-lille.fr.
Abstract:
Two poly-oxo cluster complexes of tetravalent neptunium (Np(iv)), Np38O56Cl18(bz)24(THF)8·nTHF and Np38O56Cl42(ipa)20·mipa (bz = benzoate, THF = tetrahydrofuran, and ipa = isopropanol), were obtained via solvothermal synthesis and structurally characterised by single-crystal X-ray diffraction. The {Np38} clusters are comparable to the analogous {U38} and {Pu38} motifs, filling the gap in this largest poly-oxo cluster series of tetravalent actinides.
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