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Published on: December 29, 2016
(3,5-Di-methyl-adamantan-1-yl)ammonium methane-sulfonate (memanti-nium mesylate): synthesis, structure and
Mihaela Tuksar1, Mirta Rubčić2, Ernest Meštrović1
1PLIVA Croatia Ltd., TAPI Research and Development, Prilaz baruna Filipovića 29, HR-10000 Zagreb, Croatia.
Abstract:
The asymmetric unit of the title compound, C12H22N+·CH3O3S-, consists of three (3,5-di-methyl-adamantan-1-yl)ammonium cations, C12H22N+, and three methane-sulfonate anions, CH3O3S-. In the crystal, the cations and anions associate via N-H⋯O hydrogen bonds into layers, parallel to the (001) plane, which include large supra-molecular hydrogen-bonded rings.
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