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Magnetic susceptibility and paramagnetism-based NMR

Giacomo Parigi1, Enrico Ravera1, Claudio Luchinat1

  • 1Magnetic Resonance Center (CERM) and Interuniversity Consortium for Magnetic Resonance of Metallo Proteins (CIRMMP), Via L. Sacconi 6, 50019 Sesto Fiorentino, Italy; Department of Chemistry "Ugo Schiff", University of Florence, Via della Lastruccia 3, 50019 Sesto Fiorentino, Italy.

Progress in Nuclear Magnetic Resonance Spectroscopy
|November 30, 2019
PubMed
Summary

Paramagnetism-assisted NMR studies leverage magnetic interactions for atomic-level insights. This review unifies theoretical models to explain how electron and nuclear magnetic moments report on molecular structure and dynamics.

Keywords:
Curie relaxationDipolar relaxationHyperfine shiftPseudocontact shiftResidual dipolar coupling

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