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Development-free grayscale electron beam lithography on poly (methyl methacrylate).
Wenhao Wang1,2, Zhensheng Zhang1,2,3, Xuefeng Song1,2,3
1Shenzhen Institute for Quantum Science and Engineering, Southern University of Science and Technology, Shenzhen 518055, People's Republic of China.
Nanotechnology
|July 9, 2025
Summary
This study validates a new grayscale electron beam lithography (EBL) method for direct 3D structure fabrication on PMMA membranes. The technique achieves sub-nanometer depth resolution with fewer steps and improved structure quality.
Area of Science:
- Materials Science
- Nanotechnology
- Additive Manufacturing
Background:
- Conventional electron beam lithography (EBL) methods for grayscale exposure often result in roughness and poor continuity.
- Direct fabrication of 3D structures with high resolution remains a challenge.
Purpose of the Study:
- To present and validate a novel method for direct 3D structure fabrication on poly(methyl methacrylate) (PMMA) membranes.
- To achieve precise control over the depth resolution of fabricated structures.
- To improve the quality and reduce processing steps compared to conventional EBL methods.
Main Methods:
- Utilizing grayscale electron beam lithography (EBL) for direct 3D structure fabrication.
- Implementing precise control of exposure dose for depth resolution.
- Employing a development-free approach.
- Investigating differences between 2D and 3D proximity effect correction.
- Proposing a dose correction method based on height differences.
Main Results:
- Demonstrated precise control of depth resolution to less than 1 nm.
- Achieved a development-free fabrication process, reducing processing steps.
- Minimized excessive roughness and poor continuity issues.
- Determined differences in proximity effect correction for 2D and 3D structures.
- Showcased increased edge steepness of fabricated structures using the proposed dose correction method.
Conclusions:
- The validated grayscale EBL method enables high-resolution, direct 3D structure fabrication on PMMA.
- The development-free approach and dose correction enhance fabrication efficiency and structural integrity.
- This method offers a promising advancement for nanoscale 3D patterning.

