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Updated: May 9, 2026

Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
Published on: February 15, 2016
Synthesis, crystal structure and Hirshfeld surface analysis of
Shakhnoza Mavlonova1, Giyosiddin Khayrullaev1, Dilnoza Rakhmonova1
1National University of Uzbekistan named after Mirzo Ulugbek 4 University St Tashkent 100174 Uzbekistan.
Abstract:
The title compound, C6H10N8S2, crystallizes in the monoclinic crystal system with P21/c space group. The mol-ecular geometry features a flexible ethyl-enedi-thio spacer inducing a 76.69 (11)° dihedral angle between triazole moieties; this twist precludes π-π stacking. The crystal cohesion is instead driven by a two-dimensional supra-molecular framework maintained by strong N-H⋯N hydrogen bonds and auxiliary N⋯S and C⋯S contacts. Qu-anti-tative Hirshfeld surface analysis confirms the dominance of hydrogen-involving inter-actions (98.8%), with N⋯H (40.4%) and H⋯H (27.1%) as the primary contributors to the packing arrangement.
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